Development of Low Surface Energy Fouling-Release Coating for Marine Propellers

doi:10.19423/j.cnki.31-1561/u.2024.002

Ship & Boat ›› 2025, Vol. 36 ›› Issue (03): 132-145.DOI: 10.19423/j.cnki.31-1561/u.2024.002

Development of Low Surface Energy Fouling-Release Coating for Marine Propellers

GAO Chu¹, SUN Jiawen², QIU Weiqiang¹, DUAN Jizhou²

1. Marine Design & Research Institute of China, Shanghai 200011, China;
2. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China

Received:2023-11-26 Revised:2024-02-07 Online:2025-06-25 Published:2025-07-02

螺旋桨低表面能污损脱附涂层技术进展

高处¹, 孙佳文², 邱伟强¹, 段继周²

1.中国船舶及海洋工程设计研究院上海 200011;
2.中国科学院海洋研究所青岛 266071

作者简介:高处（1984-）,男,硕士,高级工程师。研究方向：船舶设计与力学性能分析。孙佳文（1994-）,男,博士,高级工程师。研究方向：低表面能海洋防污涂层。邱伟强（1975-）,男,硕士,研究员。研究方向：船舶设计与管理。段继周（1972-）,男,博士,研究员。研究方向：海洋微生物腐蚀与生物污损。
基金资助:
国家部委重点项目（MC-201716-Z01）

Abstract

Abstract: Corrosion and biofouling impose serious hazards to the normal operation of marine propellers. The current research on the protection methods for marine propellers focuses on the propeller material itself, with insufficient attention to the propeller protective coating technology. This study introduces the anti-fouling principle of low surface energy fouling-release coatings and the development of relevant technologies, discusses the prospects and development directions of organosilicon-modified low surface energy anti-fouling coatings applied to marine propellers, and looks to the future development of anti-fouling coatings for marine propellers.

Key words: marine fouling organisms, anti-fouling coating, low surface energy, fouling-release, marine propellers

摘要： 腐蚀及生物污损严重威胁船舶螺旋桨的正常运行。当前,对于船舶螺旋桨防护方法的研究主要聚焦于材料本身,对防护涂层的关注相对不足。该文介绍了低表面能污损脱附型涂层的防污原理及相关技术的研究进展,论述了有机硅改性低表面能防污涂层应用于船舶螺旋桨的前景和发展方向,并对该领域防污涂层的未来发展进行了展望。

关键词: 海洋污损生物, 防污涂层, 低表面能, 污损脱附, 船舶螺旋桨

CLC Number:

U661.5

GAO Chu, SUN Jiawen, QIU Weiqiang, DUAN Jizhou. Development of Low Surface Energy Fouling-Release Coating for Marine Propellers[J]. Ship & Boat, 2025, 36(03): 132-145.

高处, 孙佳文, 邱伟强, 段继周. 螺旋桨低表面能污损脱附涂层技术进展[J]. 船舶, 2025, 36(03): 132-145.

References

[1] HOU B R,LI X G,MA X M,et al.The cost of corrosion in China[J].NPJ Materials Degradation,2017,1:29-33.
[2] ZHANG J Y,QIN W H,CHEN W R,et al.Integration of antifouling and anti-cavitation coatings on propellers:a review[J].Coatings,2023,13(9):1619.
[3] TIAN W,GUO Z L,WANG S L,et al.Hydrogen and DA bond-based self-healing epoxy-modified polyurea composite coating with anti-cavitation,anticorrosion,antifouling,and strong adhesion properties[J].Journal of Materials Science & Technology,2024,187:1-14.
[4] MO Y Q,XUE P H,XING J Q,et al.Conventional silicone coating improved by novel bioinspired microcavity arrays:generating stable air bubble arrays for gas-liquid interface antifouling[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,644:128887.
[5] CHEN R Z,XIE Q Y,ZENG H H,et al.Non-elastic glassy coating with fouling release and resistance abilities[J].Journal of Materials Chemistry A,2020,8(1):380-387.
[6] MAAN A M C,HOFMAN A H,DE VOS W M,et al. Recent developments and practical feasibility of polymer-based antifouling coatings[J].Advanced Functional Materials,2020,30(32):2000936.
[7] 申琳,高瑾,宋东东,等.多功能水性低表面处理涂层及涂层防护性能[J].工程科学学报,2015,37(12):1594-1600.
[8] 金承泽,张松,陈松培. 船舶螺旋桨防腐防污涂装工艺的探讨[J].造船技术,2013,41(4):39-43.
[9] BRADY R F,SINGER I L.Mechanical factors favoring release from fouling release coatings[J].Biofouling,2000,15:73-81.
[10] SELIM M S,YANG H,WANG F Q,et al.Silicone/ZnO nanorod composite coating as a marine antifouling surface[J].Applied Surface Science,2019,466:40-50.
[11] LIN X,XIE Q,MA C,et al.Self-healing,highly elastic and amphiphilic silicone-based polyurethane for antifouling coatings[J].Journal of Materials Chemistry B,2021,9(5):1384-1394.
[12] MINCHEVA R,BEIGBEDER A,JEUSETTE M,et al.On the effect of carbon nanotubes on the wettability and surface morphology of hydrosilylation-curing silicone coatings[J].Journal of Nanostructured Polymers & Nanocomposites,2009,5(2):37-43.
[13] KIM S D,JU W K,JI S I,et al.A comparative study on properties of multi-walled carbon nanotubes(MWCNTs) modified with acids and oxyfluorination[J].Journal of Fluorine Chemistry,2007,128(1):60-64.
[14] 丛巍巍,桂泰江,张凯,等.船舶螺旋桨表面防护涂层性能研究[J].材料导报,2021,35(增刊2):367-371.
[15] BRAY R F,SINGER I L.Mechanical factors favoring release from fouling release coatings[J].Biofouling,2000(15):73–81.
[16] ZHANG Z Q,XIE Q Y,ZHANG G L,et al.Surface-enriched amphiphilic polysiloxane coating with superior antifouling ability and strong substrate adhesion[J].ACS Applied Polymer Materials,2023,5(5):3524-3533.
[17] LIU Z Y,HE C J.Fabrication of amphiphilic self-healing coatings with high mechanical properties and their antifouling performance[J].Progress in Organic Coatings,2023,175:107371.
[18] LIN Y C,XIE Y F,CHEN F,et al.Bioinspired self-stratification fouling release silicone coating with strong adhesion to substrate[J].Chemical Engineering Journal,2022,446:137043.
[19] SUN J W,LIU C,DUAN J Z,et al.Facile fabrication of self-healing silicone-based poly(urea-thiourea)/tannic acid composite for anti-biofouling[J].Journal of Materials Science & Technology,2022,124:1-13.
[20] XIE Q Y,LIU C,LIN X B,et al.Nanodiamond reinforced poly(dimethylsiloxane)-based polyurea with self-healing ability for fouling release coating[J].ACS Applied Polymer Materials,2020,2(8):3181-3188.
[21] HU P,XIE Q Y,MA C F,et al.Fouling resistant silicone coating with self-healing induced by metal coordination[J].Chemical Engineering Journal,2021,406:126870.
[22] CHISHOLM B J,BOUDJOUK P,THOMAS J,et al. Anti-fouling materials containing cationic polysiloxanes:us2007/0042199[P].2007-02-22.
[23] THOMAS J,CHOI S B,FJELDHEIM R,et al.Silicones containing pendant biocides for antifouling coatings[J].Biofouling,2004,20:227-236.
[24] SUN J W,DUAN J Z,LIU X J,et al.Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties[J].Applied Materials Today,2022,28:101551.
[25] BI S Q,XU K W,SHAO G S,et al.Mechanically robust antifouling coating with dual-functional antifouling strategy by infiltrating PDMS into plasma-sprayed porous Al2O3-Cu coating[J].Journal of Materials Science & Technology,2023,159:125-137.
[26] HUANG H,ZHANG C C,CRISCI R,et al.Strong surface hydration and salt resistant mechanism of a new nonfouling zwitterionic polymer based on protein stabilizer TMAO[J].Journal of the American Chemical Society,2021,143(40):16786-16795.
[27] FAŸ F,HAWKINS M L,RÉHEL K,et al. Non-toxic,anti-fouling silicones with variable PEO-silane amphiphile content[J].Green Materials,2016,4(2):53-62.
[28] MARTINELLI E,AGOSTINI S,GALLI G,et al.Nanostructured films of amphiphilic fluorinated block copolymers for fouling release application[J].Langmuir:the ACS Journal of Surfaces and Colloids,2008,24(22):13138-13147.
[29] XIONG Y K,FANG Z Q,HU D X,et al.Nano-CeO₂-Loaded polyzwitterionic double-network high-strength hydrogel for highly enhanced synergistic marine antifouling[J].ACS Applied Materials & Interfaces,2023,15(32):38795-38807.
[30] GALHENAGE T P,HOFFMAN D,SILBERT S,et al.Fouling-release performance of silicone oil-modified siloxane polyurethane coatings[J].ACS Applied Materials & Interfaces,2016,8(42):209025-209042.
[31] MARABOTTI I,MORELLI A,ORSINI L M,et al.Fluorinated/siloxane copolymer blends for fouling release:chemical characterization and biological evaluation with algae and barnacles[J].Biofouling,2009,25:481-493.
[32] SMITH A T,LACHANCE A M,ZENG S,et al.Synthesis,properties,and applications of graphene oxide/reduced graphene oxide and their nanocomposites[J].Nano Materials Science,2019,1(1):31-47.
[33] KUMAR P,HUO P P,ZHANG R Z,et al.Antibacterial properties of graphene-based nanomaterials[J].Nanomaterials,2019,9(5):737.
[34] KORTEL M,MANSURIYA B D,VARGAS SANTANA N,et al.Graphene quantum dots as flourishing nanomaterials for bio-imaging,therapy development,and micro-supercapacitors[J].Micromachines,2020,11(9):866.
[35] NINE M J,COLE M A,TRAN D N H,et al. Graphene:a multipurpose material for protective coatings[J].Journal of Materials Chemistry A,2015,3(24):12580-12602.
[36] KRISHNAMOORTHY K,JEYASUBRAMANIAN K,PREMANATHAN M,et al.Graphene oxide nanopaint[J].Carbon,2014,72:328-337.
[37] VERMA S,MOHANTY S,NAYAK S K.Preparation of hydrophobic epoxy-polydimethylsiloxane-graphene oxide nanocomposite coatings for antifouling application[J].Soft Matter,2020,16(5):1211-1226.
[38] JIN H C,ZHANG T,BING W,et al.Antifouling performance and mechanism of elastic graphene-silicone rubber composite membranes[J].Journal of Materials Chemistry B,2019,7(3):488-497.
[39] LIU Z X,TIAN S,LI Q,et al.Integrated dual-functional ORMOSIL coatings with AgNPs@rGO nanocomposite for corrosion resistance and antifouling applications[J].ACS Sustainable Chemistry & Engineering,2020,8(17):6786-6797.
[40] SELIM M S,EL-SAFTY S A,FATTHALLAH N A,et al. Silicone/graphene oxide sheet-alumina nanorod ternary composite for superhydrophobic antifouling coating[J].Progress in Organic Coatings,2018,121:160-172.
[41] JIN H C,TIAN L M,BING W,et al.Toward the application of graphene for combating marine biofouling[J].Advanced Sustainable Systems,2021,5(1):2000076.
[42] 奚愚生,杨晓东,刘光明.溶胶‐凝胶法制备杂化材料的研究进展[J].表面技术,2012,41(3):120-123.
[43] ZHANG Y S,CHEN Z X,ZHENG H,et al.Multifunctional hard yet flexible coatings fabricated using a universal step-by-step strategy[J].Advanced Science,2022,9(14):2200268.
[44] CHEN R Z,ZHANG Y S,XIE Q Y,et al.Transparent polymer-ceramic hybrid antifouling coating with superior mechanical properties[J].Advanced Functional Materials,2021,31(19):2011145.
[45] 汤理平. 海船海船螺旋桨防腐防污问题的探讨[J].航海技术,1992(6):48.
[46] US Navy RADM Eccles:Surface Ship Energy Efficiency Initiatives[EB/OL].(2012-01-19)[2024-02-07].https://www.navsea.navy.mil/Resources/Fact-Files/Energy-Initiatives/Propeller-Coatings/.
[47] KORKUT E,ATLAR M.An experimental study into the effect of foul release coating on the efficiency,noise and cavitation characteristics of a propeller[C]//First International Symposium on Marine Propulsors smp’09,Trondheim,Norway,2009:285-293.
[48] 于雪艳,王科,张华庆,等. 船舶螺旋桨耐空泡腐蚀防污涂层研制及性能研究[J].涂料工业,2018,48(11):23-28.
[49] 赵健. 船用螺旋桨防腐防污纳米陶瓷涂层技术快速解决方案[J].船舶与海洋工程,2021,37(3):66-69.

Metrics

Tel: (021)63161688-105006
Fax: (021)63151255
E-mail: chuanbo@maric.com.cn

Copyright ©Ship & Boat
website: http://chuanbo.magtechjournal.com
京ICP备 05021913号
Advertising Business License Number: 3100120200001 Visited:

Development of Low Surface Energy Fouling-Release Coating for Marine Propellers

螺旋桨低表面能污损脱附涂层技术进展

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics